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Boc-L-Asp(OAll)-OH
Chemical name: N-alpha-t-Butyloxycarbonyl-L-aspartic acid beta-allyl ester // Synonyms: Boc-L-Asp(All)-OH, Boc-Asp(OAll)-OH, Boc-Asp(All)-OH
- Product code:BAA1072
- CAS No.:132286-77-2
- Formula:C12H19NO6
- Storage temperature:2-8°C
- Molecular weight:273,29
from €200.00
description
Building block with side protection orthogonal to Fmoc/tBu strategy. Can be used for side specific derivatization, for example for TFA mediated in situ cyclization, which is taking advantage of intermediate aspartamide formation.
references
A Tandem In Situ Peptide Cyclization through Trifluoroacetic Acid Cleavage; Koushik Chandra, Tapta Kanchan Roy, Deborah E. Shalev, Abraham Loyter, Chaim Gilon, R. BennyGerber, and Assaf Friedler; Angew. Chem. Int. Ed. 2014; 53: 9450-9455. DOI: 10.1002/anie.201402789.
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