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Fmoc-L-Glu(OtBu)-MPPA
Chemical name: N-alpha-(9-Fluorenylmethyloxycarbonyl)-L-glutamic-acid-gamma-t-butyl ester-3-(4-oxymethylphenoxy)propionic acid // Synonyms: (S)-3-(4-(((2-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)-5-(tert-butoxy)-5-oxopentanoyl)oxy)methyl)phenoxy)propanoic acid,1-[[4-(2-Carboxyethoxy)phenyl]methyl]-5-(1,1-dimethylethyl)-N-[(9H-fluoren- 9-ylmethoxy)carbonyl]-L-glutamate, Fmoc-Glu(OtBu)-
- Product code:LW00602
- CAS No.:864876-95-9
- Formula:C34H37NO9
- Storage temperature:2-8°C
- Molecular weight:603,67 g/mol
from €95.00
description
This Fmoc-amino acid-MPPA linker serves as precursor for the linkage to e.g. aminomethyl supports by standard coupling procedures. By this method, a low (max 0.5%) and reproducible epimerization level of the C-terminal amino acid in your peptide is guaranteed.
references
Improved approach for anchoring Nalpha-9-fluorenylmethyloxycarbonylamino acids as p-alkoxybenzyl esters in solid-phase peptide synthesis; F. Albericio, G. Barany; Int. J. Peptide. Protein. Res. 1985; 26(1): 92-97. https://doi.org/10.1111/j.1399-3011.1985.tb03182.x.
Amino acid derivatives used as agents bonding to a solid support; NeoMPS S.A. 2005; French Patent Application FR 0402973, International Patent Application WO2005/095332.
An Efficient Fmoc Solid-Phase Synthesis of an Amphiphile of the Neuroprotective Agent Glycyl-prolyl-glutamic Acid; P. W. R. Harris, Z.
Amso, G. P. Savage, G. T. Molenaar; Synlett 2014; 25(15): 2221-2224. https://doi.org/10.1055/s-0034-1378539.
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