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Fmoc-L-Lys(MeDmb)-OH
Nombre químico: (2S)-6-{[1-(1,3-dimethyl-2,4,6-trioxo-1,3-diazinan-5-ylidene)ethyl]amino}-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)hexanoic acid // Sinónimos: N2-(((9H-fluoren-9-yl)methoxy)carbonyl)-N6-(1-(1,3-dimethyl-2,4,6-trioxotetrahydropyrimidin-5(2H)-ylidene)ethyl)-L-lysine, Fmoc-Lys(MeDmb)-OH
- Nº Artículo:FAA8840
- Fórmula:C29H32N4O7
- Storage temperature:2-8°C
- Masa molecular:548,60 g/mol
- Pureza:min.98%
- Pureza Enantiomérica:min.99,9%
from 84,00 €
description
Novel Lysine building-block for SPPS bearing a new side-chain protecting-group. MeDmb is an orthogonal protecting group, stable under acidic and basic conditions used during SPPS and can be cleaved by a mild solution of 2% hydrazine hydrate in DMF and 2% hydroxylamine in DMF. The advantage of MeDmb over dimedone derivatives is the increased hydrophilicity, which should increase their solubility in a broad range of solvents, including green solvents.
references
Scope and Limitations of Barbituric and Thiobarbituric Amino Acid Derivatives as Protecting Groups for Solid-Phase Peptide Synthesis: Towards a Green Protecting Group; S. Ramkisson, H. H. Al-Rasheed, K. A. Dahlous, B. G. De La Torre, A. El-Faham, F. Albericio; Chem. Select 2021; 6(26): 6626-6630. https://doi.org/10.1002/slct.202101539
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All information contained in our webshop is compiled to the best of our knowledge.
Prices and product availability are subject to change and require reconfirmation. Please contact us for further information.
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