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Nombre químico: 1-(((9H-fluoren-9-yl)methoxy)carbonyl)-7-nitroindoline-5-carboxylic acid // Sinónimos: Fmoc-7-nitroindoline-5-carboxylic acid, N-alpha-(9-Fluorenylmethyloxycarbonyl)-7-nitroindoline-5-carboxylic acid
from 720,00 €
The building block can be incorporated into peptides by SPPS. The built-in photochemical function allows the decomposition of the peptide into small peptide fragments by illumination with UV light at 350 nm in aqueous solution.
Synthesis and characterization of a photocleavable collagen-like peptide; A. Ornelas, K. N. Williams, K. A. Hatch, A. Paez, A. C. Aguilar, C. E. Ellis, N. Tasnim, S. Ray, C. W. Dirk, T. Boland, B. Joddar, C. Li, K. Michael; Org. Biomol. Chem. 2018; 16: 1000-1013. https://doi.org/10.1039/C7OB02198D
Photolysis of a peptide with N-peptidyl-7-nitroindoline units using two-photon absorption; K. A. Hatch, A. Ornelas, K. N. Williams, T. Boland, K. Michael, C. Li; Biomed. Opt. Express 2016; 7(11): 4654-4659. https://doi.org/10.1364/BOE.7.004654
Efficient photochemical synthesis of peptide-á-phenylthioesters; A. Pardo, T. J. Hogenauer, Z. Cai, J. A. Vellucci, E. M. Castillo, C. W. Dirk, A. H. Franz, K. Michael; ChemBioChem 2015; 16(13): 1884-1889. http://dx.doi.org/10.1002/cbic.201500266
Virtually epimerization-free synthesis of peptide-á-thioesters; T. J. Hogenauer, Q. Wang, A. K. Sanki, A. J. Gammon, C. H. L. Chu, C. M. Kaneshiro, Y. Kajihara, K. Michael; Org. Biomol. Chem. 2007; 5: 759-762. https://doi.org/10.1039/B618442A
A New Photolabile Linker for the Photoactivation of Carboxyl Groups; K. C. Nicolaou, B. S. Safina, N. Winssinger; Synlett 2001; SI: 900-903.
