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Fmoc-L-Ser(Msbh)-OH
Nom chimique: N-alpha-(9-Fluorenylmethyloxycarbonyl)-S-(4,4'-dimethylsulfinylbenzhydryl)-L-serine // Synonymes: N-(((9H-fluoren-9-yl)methoxy)carbonyl)-O-(bis(4-(methylsulfinyl)phenyl)methyl)-L-serine, Fmoc-Ser(Msbh)-OH, Safety-Catch L-Serine
- n° Art.:FAA8835
- n° CAS:2919325-46-3
- Formule:C33H31NO7S2
- Storage temperature:2-8°C
- Masse moléculaire:617,73 g/mol
from 375,00 €
description
A Fmoc protected L-Cysteine for SPSS, with an MsbH protected thiol group. The MsbH protecting group is removed by reduction of the sulfoxides, followed by acidolysis with TFA.
references
The p-(methylsulfinyl)benzyl group: a trifluoroacetic acid (TFA)-stable carboxyl-protecting group readily convertible to a TFA-labile group; J. M. Samanen, E. Brandeis; J. Org. Chem. 1988; 53(3): 561-569. https://doi.org/10.1021/jo00238a016
Solid-Phase Synthesis Using a Four-Dimensional (Safety-Catch) Protecting Group Scheme; F. Albericio, S. Noki, E. Brasil, H. Zhang, T. Bruckdorfer, B. G. de la Torre; J. Org. Chem. 2022; 87: 9443-9453. https://doi.org/10.1021/acs.joc.2c01056
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All information contained in our webshop is compiled to the best of our knowledge.
Prices and product availability are subject to change and require reconfirmation. Please contact us for further information.
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