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H-L-His(2-Thio)-OH
Chemischer Name: (S)-2-amino-3-(2-thioxo-2,3-dihydro-1H-imidazol-4-yl)propanoic acid // Synonyme: H-2-Thio-L-Histidine, Thiohistidine, H-His(2-Thio)-OH
- Art-Nr.:HAA9290
- CAS Nr.:2002-22-4
- Lagertemperatur:2-8°C
- Formel:C6H9N3O2S
- Molare Masse:187,22 g/mol
Ab 150,00 €
description
An analogue of ergothioneine, which can be incorporated into peptides to increase the antioxidant capacity of the peptide.
references
Short protecting-group-free synthesis of 5-acetylsulfanyl-histidines in water: novel precursors of 5-sulfanyl-histidine and its analogues; Org. Biomol. Chem. 2016; 14: 10473-10480. https://doi.org/10.1039/C6OB01870J.
Improved synthesis of the super antioxidant, ergothioneine, and its biosynthetic pathway intermediates; P. L. Khonde, A. Jardine; Org. Biomol. Chem. 2015; 13: 1415-1419. https://doi.org/10.1039/C4OB02023E.
Cysteine as a suitable sulfur reagent for the protecting-group-free synthesis of sulfur-containing amino acids: biomimetic synthesis of L-ergothioneine in water; I. Erdelmeier, S. Daunay, R. Lebel, L. Farescour, J.-C. Yadan; Green Chem. 2012; 14: 2256-2265. https://doi.org/10.1039/C2GC35367A.
Role of 2-oxo and 2-thioxo modifications on the fragmentation reactions of histidine radical cation; Rapid Commun. Mass Spectrom. 2011; 25: 251-261.
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