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Fmoc-L-trans-Hyp(Nfb)-OH
Nom chimique: N-alpha-(9-Fluorenylmethyloxycarbonyl)-O-(nonafluoro-t-butyl)-trans-L-hydroxyproline // Synonymes: Fmoc-Hyp(nonafluoro-t-butyl)-OH (trans), (2S,4R)-1-(((9H-fluoren-9-yl)methoxy)carbonyl)-4-(1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-yloxy)pyrrolidine-2-carboxylic acidFmoc-L-Hyp(Nfb)-OH (t rans), Fmoc-L-Hyp(Nfb)-OH (2S,4R), Fmoc-trans-Hyp(
- n° Art.:FAA4560
- n° CAS:1622172-75-1
- Formule:C24H18F9NO5
- Storage temperature:2-8°C
- Masse moléculaire:571,39 g/mol
from 900,00 €
description
The nonafluoro-t-butyl group (Nfb) equips the proline moiety with both polarity and hydrophobicity. It is stable to standard SPPS cleavage conditions for Wang typical linkers, like 90% TFA/10% scavengers.
references
(2S,4R)- and (2S,4S)-Perfluoro-tert-butyl 4-Hydroxyproline: Two Conformationally Distinct Proline Amino Acids for Sensitive Application in 19F NMR; Caitlin M. Tressler and Neal J. Zondlo; J. Org. Chem. 2014; 79: 5880−5886; DOI: org/10.1021/jo5008674
ã-(S)-Trifluoromethyl proline: evaluation as a structural substitute of proline for solid state 19F-NMR peptide studies; Vladimir Kubyshkin, Sergii Afonin, Sezgin Kara, Nediljko Budisa, Pavel K. Mykhailiuk, Anne S. Ulrich; Org. Biomol. Chem. 2015; 13: 3171-3181; DOI: 10.1039/c5ob00034c.
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All information contained in our webshop is compiled to the best of our knowledge.
Prices and product availability are subject to change and require reconfirmation. Please contact us for further information.
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