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Fmoc-L-Glu(ODmab)-OH
Nom chimique: N-alpha-(9-Fluorenylmethyloxycarbonyl)-L-glutamic-acid-gamma-[N-{1-(4,4-dimethyl-2,6-dixocyclohexylidene-3-methylbutyl}amino]benzyl ester // Synonymes: 5-[[4-[[1-(4,4-Dimethyl-2,6-dioxocyclohexylidene)-3-methylbutyl]amino]phenyl]methyl] hydrogen N-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-glutamate,(2S)-5-[[4-[[1-(4,4-Dimethyl-2,6-dioxocyclohexylidene)- 3-methylbutyl]amino]phenyl]methoxy]-2-(9H-fluoren-
- n° Art.:FAA8555
- n° CAS:268730-86-5
- Formule:C40H44N2O8
- Storage temperature:-20°C
- Masse moléculaire:680,80 g/mol
from 240,00 €
description
The 4-{N-[1-(4,4-dimethyl-2,6-dioxocyclohexylidene)-3-methylbutyl]amino}benzyl (Dmab) protecting group is compatible with the Fmoc/tert-butyl strategy used in standard peptide chemistry and is not cleaved during the final TFA treatment. Dmab esters are easily removed on solid phase or in solution using 2% hydrazine.
references
References:
A new photolabile carboxyl protecting group for native chemical ligation; B. Briand, N. Kotzur, V. Hagen, M. Beyermann; Tetrahedron Lett. 2008; 49(1): 85-87. https://doi.org/10.1016/j.tetlet.2007.11.028.
Development of Conformationally Constrained a-RgIAAnalogues as Stable Peptide Antagonists of Human a9a10Nicotinic Acetylcholine Receptors; N. Zheng, S. B. Christensen, A. Blakely, C. Dowel, L. Purushottam, J. M. McIntosh, D. H.-C. Chou; J. Med. Chem. 2020; 63(15): 8380-8387. https://doi.org/10.1021/acs.jmedchem.0c00613.
Secondary structural preferences of some antibacterial cyclooctapeptides in the presence of calcium(II); T. Stevens, N. McNeil, X. Lin, M. Ngu-Schwemlein; Int. J. Med. Chem. 2012. https://doi.org/10.1155/2012/730239.
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All information contained in our webshop is compiled to the best of our knowledge.
Prices and product availability are subject to change and require reconfirmation. Please contact us for further information.
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