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Fmoc-D-Lys(Dde)-OH
Nom chimique: N-alpha-(9-Fluorenylmethyloxycarbonyl)-N-epsilon-[(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)ethyl]-D-lysine // Synonymes: N-alpha-Fmoc-N-epsilon-Dde-D-lysine, Fmoc-D-Lys(Dde)
- n° Art.:FAA1486
- n° CAS:333973-51-6
- Storage temperature:2-8°C
- Formule:C31H36N2O6
- Masse moléculaire:532,64 g/mol
- Pureté:min. 99%
- Pureté Énantiomérique:min. 99,7%
from 70,00 €
description
Building block with side protection orthogonal to Fmoc/tBu strategy. Can be used for side specific derivatization, for example for TFA mediated in situ cyclization, which is taking advantage of intermediate aspartamide formation.
references
A Tandem In Situ Peptide Cyclization through Trifluoroacetic Acid Cleavage; Koushik Chandra, Tapta Kanchan Roy, Deborah E. Shalev, Abraham Loyter, Chaim Gilon, R. Benny Gerber, and Assaf Friedler; Angew. Chem. Int. Ed. 2014; 53: 9450-9455. DOI: 10.1002/anie.201402789.
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