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Fmoc-D-Dap(Ns)-OH
Nom chimique: N-alpha-(9-Fluorenylmethyloxycarbonyl)-N-beta-nosyl-D-2,3-diaminopropionic acid // Synonymes: Fmoc-D-Dapa(Ns)-OH, Fmoc-D-Dpr(Ns)-OH, Fmoc-D-Dap(Ns), Fmoc-D-Dap(Ns)-OH, Fmoc-D-Dap(Nosyl),(2R)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-(2-nitrobenzenesulfonamido)propanoic acid, N-alpha-Fm oc-N-beta-Ns-D-2,3-diaminopropionic acid
- n° Art.:FAA7650
- n° CAS:487027-90-7
- Formule:C24H21N3O8S
- Storage temperature:2-8°C
- Masse moléculaire:511,5 g/mol
- Pureté:min. 98%
- Pureté Énantiomérique:min. 99,7%
from 90,00 €
description
Used as an orthogonally protected Dap building-block in SPPS. The Nosyl-group can be utilized to enable Mitsunobu-reaction or N-alkylations at the side-chain N atom.
references
Solid-Phase Synthesis of Amine-Bridged Cyclic Enkephalin Analogues via On-Resin Cyclization Utilizing the Fukuyama−Mitsunobu Reaction; Yosup Rew, Murray Goodman; J. Org. Chem. 2002; 67(25): 8820-8826. DOI: 10.1021/jo020447l.
Synthetic strategy for side chain mono-N-alkylation of Fmoc-amino acids promoted by molecular sieves. Monfregola L., De Luca S.; Amino Acids 2011; 41(4): 981-990. DOI: 10.1007/s00726-010-0798-6.
New synthetic strategy for o-NBS protected amino acids and their use in synthesis of mono-benzylated peptides; Stefano de Luca, Raffaella Della Moglie, Antonia De Capua, Giancarlo Morelli;
Tetrahedron Lett. 2005; 46(39): 6637-6640. DOI: 10.1016/j.tetlet.2005.07.154.
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All information contained in our webshop is compiled to the best of our knowledge.
Prices and product availability are subject to change and require reconfirmation. Please contact us for further information.
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