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Fmoc-L-His(2-Thio)-OH
Nom chimique: (S)-2-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)-3-(2-thioxo-2,3-dihydro-1H-imidazol-4-yl)propanoic acid // Synonymes: Fmoc-2-Thio-L-Histidine, Fmoc-His(2-Thio)-OH
- n° Art.:FAA8810
- n° CAS:2851463-63-1
- Formule:C21H19N3O4S
- Storage temperature:-20°C
- Masse moléculaire:409,46 g/mol
from 150,00 €
description
An analogue of ergothioneine, which can be incorporated into peptides to increase the antioxidant capacity of the peptide.
references
Short protecting-group-free synthesis of 5-acetylsulfanyl-histidines in water: novel precursors of 5-sulfanyl-histidine and its analogues; Org. Biomol. Chem. 2016; 14: 10473-10480. https://doi.org/10.1039/C6OB01870J.
Improved synthesis of the super antioxidant, ergothioneine, and its biosynthetic pathway intermediates; P. L. Khonde, A. Jardine; Org. Biomol. Chem. 2015; 13: 1415-1419. https://doi.org/10.1039/C4OB02023E.
Cysteine as a suitable sulfur reagent for the protecting-group-free synthesis of sulfur-containing amino acids: biomimetic synthesis of L-ergothioneine in water; I. Erdelmeier, S. Daunay, R. Lebel, L. Farescour, J.-C. Yadan; Green Chem. 2012; 14: 2256-2265. https://doi.org/10.1039/C2GC35367A.
Role of 2-oxo and 2-thioxo modifications on the fragmentation reactions of histidine radical cation; Rapid Commun. Mass Spectrom. 2011; 25: 251-261.
Ergothioneine in a peptide: Substitution of histidine with 2-thiohistidine in bioactive peptides: K. A. Jenny, E. L. Ruggles, M. D. Liptak, D. S. Masterson, R. J. Hondal; J. Pept. Sci. 2021; 27(10): e3339.
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All information contained in our webshop is compiled to the best of our knowledge.
Prices and product availability are subject to change and require reconfirmation. Please contact us for further information.
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