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Boc-L-Lys(Ns)-OH
Chemischer Name: N-alpha-t-Butyloxycarbonyl-N-epsilon-nosyl-L-lysine // Synonyme: Boc-Lys(Ns)-OH,N-alpha-Boc-N-epsilon-nosyl-L-lysine,N-alpha-Boc-N-epsilon-(2-nitrobenzenesulfonyl)-L-lysine,N-alpha-Boc-N-epsilon-(2-nitrophenylsulfonyl)-L-lysine,(S)-2-(tert-butoxycarbonylami no)-6-(2-nitrophenylsulfonamido)hexanoic acid,(S)-
- Art-Nr.:BAA5230
- CAS Nr.:1301706-36-4
- Lagertemperatur:2-8°C
- Formel:C17H25N3O8S
- Molare Masse:431,5 g/mol
Ab 200,00 €
description
Building block with side protection orthogonal to Fmoc/tBu strategy. Can be used for side specific derivatization, for example for TFA mediated in situ cyclization, which is taking advantage of intermediate aspartamide formation.
references
A Tandem In Situ Peptide Cyclization through Trifluoroacetic Acid Cleavage; Koushik Chandra, Tapta Kanchan Roy,
Deborah E. Shalev, Abraham Loyter, Chaim Gilon, R. Benny Gerber, and Assaf Friedler; Angew. Chem. Int. Ed. 2014;
53: 9450-9455. DOI: 10.1002/anie.201402789.
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