Fmoc-L-Tyr(Msib)-OH

Chemical name: (2S)-2-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)-3-(4-((4-(methylsulfinyl)benzyl)oxy)phenyl)propanoic acid // Synonyms: Fmoc-Tyr(Msib)-OH, (2S)-2-(Fmoc)-3-(4-((4-(methylsulfinyl)benzyl)oxy)phenyl)propanoic acid, N-[(9H-fluoren-9-ylmethoxy)carbonyl]-O-[[4-(methylsulfinyl)phenyl]methyl]-L-Tyrosine,N-Fmoc-O-[[4-(methyls ulfinyl)phenyl]methyl]-L-Tyrosine, safety catch Fm

  • Product code:FAA7885
  • CAS No.:156125-68-7
  • Storage temperature:2-8°C
  • Formula:C32H29NO6S
  • Molecular weight:555.65 g/mol

from $1,125.00

Grouped product items
Qty Packing unit Price SKU Availability
1 g
$1,125.00
FAA7885.0001
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description

A Fmoc protected L-Tyrosine for SPSS, with an Msib protected phenolic hydroxyl group. The Msib protecting group is removed by reduction of the sulfoxide, followed by acidolysis with TFA.


references

Solid-Phase Peptide Synthesis Using a Four-Dimensional (Safety-Catch) Protecting Group Scheme; S. Noki, E. Brasil, H. Zhang, T. Bruckdorfer, B. de la Torre, F. Albericio; J. Org. Chem. 2022; 87(15): 9443–9453. https://doi.org/10.1021/acs.joc.2c01056


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