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Fmoc-L-Lys(ivDde)-OH
Chemical name: N-alpha-(9-Fluorenylmethyloxycarbonyl)-N-epsilon-[1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)-3-methylbutyl]-L-lysine // Synonyms: N-alpha-Fmoc-N-epsilon-ivDde-L-lysine, Fmoc-Lys(ivDde)-OH
- Product code:FAA1500
- CAS No.:204777-78-6
- Storage temperature:2-8°C
- Formula:C34H42N2O6
- Molecular weight:574.72 g/mol
- Purity :min. 98%
- Enantiomeric Purity:min. 99,9%
from €56.00
description
Building block with side protection orthogonal to Fmoc/tBu strategy. Can be used for side specific derivatization, for example for TFA mediated in situ cyclization, which is taking advantage of intermediate aspartamide formation.
references
A Tandem In Situ Peptide Cyclization through Trifluoroacetic Acid Cleavage; Koushik Chandra, Tapta Kanchan Roy, Deborah E. Shalev, Abraham Loyter, Chaim Gilon, R. BennyGerber, and Assaf Friedler; Angew. Chem. Int. Ed. 2014; 53: 9450-9455. DOI: 10.1002/anie.201402789.
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