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Fmoc-Gly-MPPA
Nom chimique: N-alpha-(9-Fluorenylmethyloxycarbonyl)-glycine-3-(4-oxymethylphenoxy)propionic acid // Synonymes: 3-(4-((((((9H-fluoren-9-yl)methoxy)carbonyl)glycyl)oxy)methyl)phenoxy)propanoic acid, N-[(9H-Fluoren-9-ylmethoxy)carbonyl]glycine-[4-(2-carboxyethoxy)phenyl]methyl ester
- n° Art.:LW00802
- n° CAS:130914-04-4
- Formule:C27H25NO7
- Storage temperature:2-8°C
- Masse moléculaire:475,50 g/mol
from 75,00 €
description
This Fmoc-amino acid-MPPA linker serves as precursor for the linkage to e.g. aminomethyl supports by standard coupling procedures. By this method, a low (max 0.5%) and reproducible epimerization level of the C-terminal amino acid in your peptide is guaranteed.
references
Improved approach for anchoring Nalpha-9-fluorenylmethyloxycarbonylamino acids as p-alkoxybenzyl esters in solid-phase peptide synthesis; F. Albericio, G. Barany; Int. J. Peptide. Protein. Res. 1985; 26(1): 92-97. https://doi.org/10.1111/j.1399-3011.1985.tb03182.x.
Amino acid derivatives used as agents bonding to a solid support; NeoMPS S.A. 2005; French Patent Application FR 0402973, International Patent Application WO2005/095332.
Synthesis of Natural Cyclopentapeptides Isolated from Dianthus chinensis; S. Zhang, Z. Amso, L. M. De Leon Rodriguez, H. Kaur, M. A. Brimble; J. Nat. Prod. 2016; 79(7): 1769-1774. https://doi.org/10.1021/acs.jnatprod.6b00152.
Synthesis and in vitro bone cell activity of analogues of the cyclohexapeptide dianthin G; Z. Amso, R. Kowalczyk, Y.-E. Park, M. Watson, J.-M. Link, D. S. Musson, J. Cornish, M. A. Brimble; Org. Biomol. Chem. 2016; 14: 6231-6243. https://doi.org/10.1039/C6OB00983B.
Synthesis and biological evaluation of the osteoblast proliferating cyclic peptides dianthins G and H; H. Kaur, A. M. Heapy, R. Kowalczyk, Z. Amso, M. Watson, J. Cornish, M. A. Brimble; Tetrahedron 2014; 70(42): 7788-7794. https://doi.org/10.1016/j.tet.2014.04.035.
Synthesis of the Antifungal Cyclic Peptides Tunicyclins C and D; H. Kaur, A. M. Heapy, M. A. Brimble; Synlett 2012; 2: 275-277. https://doi.org/10.1055/s-0031-1290071.
Synthesis of monolysyl advanced glycation endproducts and their incorporation into collagen model peptides; T. M. Woods, M. Kamalov, P. W. R. Harris, G. J. S. Cooper, M. Brimble; Org. Lett. 2012; 14(22): 5740-5743. https://doi.org/10.1021/ol302745f.
Gly/Lys-containing peptide macrocycles: Synthesis and cyclization studies; E. Crusi, J. M. Huerta, D. Andreu, E. Giralt; Tetrahedron Lett. 1990; 31(29): 4191-4194. https://doi.org/10.1016/S0040-4039(00)97579-8.
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All information contained in our webshop is compiled to the best of our knowledge.
Prices and product availability are subject to change and require reconfirmation. Please contact us for further information.
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