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Fmoc-L-Lys(Mtt)-OH
Nom chimique: N-alpha-(9-Fluorenylmethyloxycarbonyl)-N-epsilon-4-methyltrityl-L-lysine // Synonymes: Fmoc-Lys(Mtt)-OH
- n° Art.:FAA1135
- n° CAS:167393-62-6
- Formule:C41H40N2O4
- Storage temperature:2-8°C
- Masse moléculaire:624,8 g/mol
from 120,00 €
description
Building block with side protection orthogonal to Fmoc/tBu strategy. Can be used for side specific derivatization, for example for TFA mediated in situ cyclization, which is taking advantage of intermediate aspartamide formation.
references
A Tandem In Situ Peptide Cyclization through Trifluoroacetic Acid Cleavage; Koushik Chandra, Tapta Kanchan Roy, Deborah E. Shalev, Abraham Loyter, Chaim Gilon, R. Benny Gerber,
and Assaf Friedler; Angew. Chem. Int. Ed. 2014; 53: 9450-9455. DOI: 10.1002/anie.201402789.
Preparation of the very acid-sensitive Fmoc-Lys(Mtt)-OH. Application in the synthesis of side-chain to side-chain cyclic peptides and oligolysine cores suitable for the
solid-phase assembly of MAPs and TASPs; A. Aletras, K. Barlos, D. Gatos, S. Koutsogianni and P. Mamos; International journal of peptide and protein research 1995; 45: 488-96.
Synthesis of Modified Peptides; S. L. Mellor, D. A. Wellings, J.-A. Fehrentz, M. Paris, J. Martinez, N. J. Ede, A. M. Bray, D. J. Evans and G. B. Bloomberg; ChemInform 2000; 31:
no-no. doi:10.1002/chin.200043243
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All information contained in our webshop is compiled to the best of our knowledge.
Prices and product availability are subject to change and require reconfirmation. Please contact us for further information.
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