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Fmoc-L-Arg(Pbf)-MPPA
Chemical name: N-alpha-(9-Fluorenylmethyloxycarbonyl)-N'-2,2,4,6,7-pentamethyldihydrobenzofuran-5-sulfonyl-L-arginine-3-(4-oxymethylphenoxy)propionic acid // Synonyms: 3-(4-(((N2-(((9H-fluoren-9-yl)methoxy)carbonyl)-N-omega-((2,2,4,6,7-pentamethyl-2,3-dihydrobenzofuran-5-yl)sulfonyl)-L-arginyl)oxy)methyl)phenoxy)propanoic acid,N-[(9H-Fluoren-9-ylmethoxy)carbonyl]- N'-2,2,4,6,7-pentamethyldihydrobenzofuran-5-sulfon
- Product code:LW00203
- CAS No.:1202179-60-9
- Formula:C44H50N4O10S
- Molecular weight:826.96 g/mol
from $187.50
description
This Fmoc-amino acid-MPPA linker serves as precursor for the linkage to e.g. aminomethyl supports by standard coupling procedures. By this method, a low (max 0.5%) and reproducible epimerization level of the C-terminal amino acid in your peptide is guaranteed.
references
Improved approach for anchoring Nalpha-9-fluorenylmethyloxycarbonylamino acids as p-alkoxybenzyl esters in solid-phase peptide synthesis; F. Albericio, G. Barany; Int. J. Peptide. Protein. Res. 1985; 26(1): 92-97. https://doi.org/10.1111/j.1399-3011.1985.tb03182.x.
Amino acid derivatives used as agents bonding to a solid support; NeoMPS S.A. 2005; French Patent Application FR 0402973, International Patent Application WO2005/095332.
Chemical synthesis of a polypeptide backbone derived from the primary sequence of the cancer protein NY-ESO-1 enabled by kinetically controlled ligation and pseudoprolines; P. W. R. Harris, M. A. Brimble; Pept. Sci. 2015; 104(2): 116-127. https://doi.org/10.1002/bip.22621.
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